| 钡离子为底的十甲基五元瓜环分子碗 |
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| 引用本文： | 赵云洁,薛赛凤,祝黔江,张云黔,陶朱,魏赞斌,龙腊生. 钡离子为底的十甲基五元瓜环分子碗[J]. 无机化学学报, 2006, 22(1): 129-133 |
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| 作者姓名： | 赵云洁 薛赛凤 祝黔江 张云黔 陶朱 魏赞斌 龙腊生 |
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| 作者单位： | 1. 贵州大学应用化学研究所,贵阳,550025
2. 厦门大学化学系,厦门,361005 |
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| 基金项目： | 中国科学院资助项目;科技部国际科技合作项目;贵州省省长基金;贵州省国际科技合作项目 |
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| 摘 要： | A molecular bowl with barium ion covering one portal of decamethylcucurbit[5]uril as a ‘metal-ion-bottom’ has been synthesized. The structure of the molecular bowl has been confirmed by the single crystal X-ray diffraction determination. It belongs to orthorhombic with space group of Pna21. The crystal unit cell parameters are: a=3.210 8(6) nm, b=1.474 2(3) nm, c=1.151 6(2) nm, and V=5.450 9(18) nm3, Dc=1.677 Mg·m-3, Z=4, F(000)=2 832, R=0.055 1, wR=0.156 8. CCDC: 290552.
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| 关 键 词： | 钡离子； 十甲基五元瓜环； 分子碗； 晶体结构 |
| 文章编号： | 1001-4861(2006)01-0129-05 |
| 收稿时间： | 2005-03-28 |
| 修稿时间： | 2005-11-07 |
A Molecular Bowl with Barium Ion As Bottom |
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| ZHAO Yun-Jie,XUE Sai-Feng,ZHU Qian-Jiang,ZHANG Yun-Qian,TAO Zhu,WEI Zhan-Bing and LONG La-Sheng. A Molecular Bowl with Barium Ion As Bottom[J]. Chinese Journal of Inorganic Chemistry, 2006, 22(1): 129-133 |
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| Authors: | ZHAO Yun-Jie XUE Sai-Feng ZHU Qian-Jiang ZHANG Yun-Qian TAO Zhu WEI Zhan-Bing LONG La-Sheng |
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| Affiliation: | Institute of Applied Chemistry, Guizhou University, Guiyang 550025,Institute of Applied Chemistry, Guizhou University, Guiyang 550025,Institute of Applied Chemistry, Guizhou University, Guiyang 550025,Institute of Applied Chemistry, Guizhou University, Guiyang 550025,Institute of Applied Chemistry, Guizhou University, Guiyang 550025,Department of Chemistry, Xiamen University, Xiamen, Fujian 361005 and Department of Chemistry, Xiamen University, Xiamen, Fujian 361005 |
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| Abstract: | |
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| Keywords: | barium iron decamethylcucurbit[5]uril molecular bowl crystal structure |
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