Synthesis of Crystalline Chalcogenides in Ionic Liquids

Crystalline chalcogenides belong to the most promising class of materials. In addition to dense solid‐state structures, they may form molecular cluster arrangements and networks with high porosity, as in the so‐called “zeotype” chalcogenidometalates. The high structural diversity comes along with interesting physical properties such as semi‐/photoconductivity, ion transport capability, molecular trapping potential, as well as chemical and catalytic activity. The great interest in the development of new and tailored chalcogenides has provoked a continuous search for new and better synthesis strategies over the years. The trend has clearly been towards lower temperatures for both economic and ecological reasons as well as for better reaction control. This led to the application of ionic liquids as a designer‐like medium for materials synthesis. In this Review, we summarize recent developments and present a survey of different chalcogenide families along with their properties.