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Selective Catalytic Synthesis Using the Combination of Carbon Dioxide and Hydrogen: Catalytic Chess at the Interface of Energy and Chemistry
Authors:Prof. Dr. Jürgen Klankermayer  Sebastian Wesselbaum  Dr. Kassem Beydoun  Prof. Dr. Walter Leitner
Affiliation:1. Institut für Technische und Makromolekulare Chemie, RWTH Aachen University, Aachen, Germany;2. Max-Planck-Institut für Kohlenforschung, Mülheim an der Ruhr, Germany
Abstract:The present Review highlights the challenges and opportunities when using the combination CO2/H2 as a C1 synthon in catalytic reactions and processes. The transformations are classified according to the reduction level and the bond‐forming processes, covering the value chain from high volume basic chemicals to complex molecules, including biologically active substances. Whereas some of these concepts can facilitate the transition of the energy system by harvesting renewable energy into chemical products, others provide options to reduce the environmental impact of chemical production already in today's petrochemical‐based industry. Interdisciplinary fundamental research from chemists and chemical engineers can make important contributions to sustainable development at the interface of the energetic and chemical value chain. The present Review invites the reader to enjoy this exciting area of “catalytic chess” and maybe even to start playing some games in her or his laboratory.
Keywords:catalysis  CO2 hydrogenation  green chemistry
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