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Template‐Free Synthesis of a Molecular Solomon Link by Two‐Component Self‐Assembly |
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| Authors: | Young Ho Song Dr Nem Singh Dr Jaehoon Jung Dr Hyunuk Kim Eun‐Hee Kim Dr Hae‐Kap Cheong Dr Yousoo Kim Prof Ki‐Whan Chi |
| Institution: | 1. Department of Chemistry, University of Ulsan, Ulsan, Republic of Korea;2. Energy Materials Laboratory, Korea Institute of Energy Research, Daejeon, Republic of Korea;3. Protein Structure Group, Korea Basic Science Institute, Chungbuk, Republic of Korea;4. Surface and Interface Science Laboratory, RIKEN, Wako, Saitama, Japan |
| Abstract: | A molecular Solomon link was synthesized in high yield through the template‐free, coordination‐driven self‐assembly of a carbazole‐functionalized donor and a tetracene‐based dinuclear ruthenium(II) acceptor. The doubly interlocked topology was realized by a strategically chosen ligand which was capable of participating in multiple CH ??? π and π–π interactions, as evidenced from single‐crystal X‐ray analysis and computational studies. This method is the first example of a two‐component self‐assembly of a molecular Solomon link using a directional bonding approach. The donor alone was not responsible for the construction of the Solomon link, and was confirmed by its noncatenane self‐assemblies obtained with other similar ruthenium(II) acceptors. |
| Keywords: | noncovalent interactions self-assembly structure elucidation supramolecular chemistry X-ray diffraction |