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Solution‐Liquid‐Solid Synthesis of Hexagonal Nickel Selenide Nanowire Arrays with a Nonmetal Catalyst
Authors:Dr Kun Xu  Hui Ding  Kaicheng Jia  Xiuli Lu  Pengzuo Chen  Tianpei Zhou  Han Cheng  Si Liu  Prof Changzheng Wu  Prof Yi Xie
Institution:Hefei National Laboratory for Physical Science at the Microscale, iChEM(Collaborative Innovation Center of Chemistry for Energy Materials), Hefei Science Center (CAS), CAS Key Laboratory of Mechanical Behavior and Design of Materials, University of Science & Technology of China, Hefei, Anhui, P. R. China
Abstract:Inorganic nanowire arrays hold great promise for next‐generation energy storage and conversion devices. Understanding the growth mechanism of nanowire arrays is of considerable interest for expanding the range of applications. Herein, we report the solution‐liquid‐solid (SLS) synthesis of hexagonal nickel selenide nanowires by using a nonmetal molecular crystal (selenium) as catalyst, which successfully brings SLS into the realm of conventional low‐temperature solution synthesis. As a proof‐of‐concept application, the NiSe nanowire array was used as a catalyst for electrochemical water oxidation. This approach offers a new possibility to design arrays of inorganic nanowires.
Keywords:electrochemistry  heterogeneous catalysis  nanostructures  oxidation  selenium
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