Thermolysis of complex cyanides,XX. thermal decomposition of Zn[Fe (CN)5NO] · 3H2O and identification of the products of decomposition |
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Authors: | B Mohai A Horváth P E Honti |
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Institution: | (1) Department of General and Inorganic Chemistry, Veszprém University of Chemical Engineering, Hungary |
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Abstract: | The thermal decomposition of ZnFe (CN)5NO] was studied by thermal analysis, IR and Mössbauer spectroscopy. The experimental results showed that the decomposition starts with cyanogen formation, giving a tetracoordinated cyano-nitrosyl intermediate. The NO ligand elimination is followed by a structural rearrangement to FeZn (CN)4].
Zusammenfassung Die thermische Zersetzung von ZnFe (CN)5NO] wurde derivatographisch und mittels IR- und Mössbauer-Spektroskopie untersucht. Die Zersetzung beginnt mit Dizyanentwicklung unter Bildung eines tetrakoordinierten Cyano-nitrosyl-Intermediärs. Der Eliminierung des NO-Liganden folgt eine zu FeZn (CN)4] führende strukturelle Umordnung.
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