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Linewidths of HCl broadened by CO2 and N2 and CO broadened by CO2
Authors:Robert A Toth  Lane A Darnton
Institution:Jet Propulsion Laboratory, 4800 Oak Grove Drive, Pasadena, California 91103 USA;Department of Physics, University of California, Santa Barbara, California 93106 USA
Abstract:High resolution measurement of the linewidths of HCl broadened by CO2 and N2 and CO broadened by CO2 have been performed in both the 1-0 and 2-0 bands of HCl and the 2-0 band of CO. The data were analyzed by the direct and the peak absorption methods. Values of the linewidths obtained by the two methods are in good agreement. For |m| ≤ 3, for the case of HCl + CO2, the agreement is good for the values obtained in both bands of HCl. However for |m| > 3, the HCl + CO2 linewidths in the 1-0 band are smaller than the corresponding lines in the 2-0 band by as much as 11% for |m| = 9. Lines (|m| ≤ 3) of the 1-0 and 2-0 bands of HCl broadened by CO2 were also analyzed in terms of the super-Lorentzian line profile proposed by Varanasi, S. K. Sarangi, and G. D. T. Tejwani (J. Quan. Spectr. Radiative Transfer12, 857 (1972)) and the Lorentzian profile. The results indicate that near the line center (within 3γ), the shape of HCl + CO2 lines are Lorentzian.
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