Non planéité de cyclopenténones substituées analyse conformationnelle par résonance magnétique nucléaire |
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Authors: | Mme G Hajdukovic Mme ML Martin |
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Institution: | Laboratoire de Chimie Organique Physique, Équipe associée au C.N.R.S. No. 313, U.E.R. de Chimie, B.P. 1044, 44000-NantesFrance |
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Abstract: | The stereochemistry of substituted cyclopent-2-en-1-ones was studied by NMR. The existence of non-planar rings is indicated and conformational analysis, based principally upon examination of the coupling constants enables the conformational population to be estimated; trans dihalogeno derivatives, for example, occur predominantly in the diaxial form. |
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Keywords: | Adresse permanente: Laboratoire de Chimie Physique Institut “Boris Kidri?” B P 522 Belgrade Yougoslavie |
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