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Forces d'oscillateur du potassium
Authors:J.N. Le Toulouzan  R. Darrigo  P. Valentin
Affiliation:Laboratoires de Thermodynamique de l''Université de Rouen, E.R.A. C.N.R.S. n° 254 et Laboratoires de l''Inscir, 76130 Mont-Saint-Aignan, France
Abstract:We describe the results of measurements on emission and absorption of potassium I lines obtained in two series of experiments. The first concerns a low-pressure flame fed by a methane and oxygen mixture, seeded with potassium carbonate, and the other an atmospheric- pressure helium plasma seeded with potassium.A collation of the experimental results of the latter series and Drawin's theory about the conditions of validity for local thermodynamic equilibrium show that the transition-probability values measured by Heiërman are incorrect. Warner's theoretical values are more satisfactory. This study allows us to propose new oscillator strengths for the KI lines corresponding to the following transitions: 42P012 ? 72S12, 42P012 ? 102S32 ? 112S12 of the sharp series and 42P032 ? 62D3252 of the diffuse series.
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