C-H amination in synthesis: an approach to the assembly of the B/C/D ring system of aconitine |
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Authors: | Conrad Rosemary M Du Bois J |
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Affiliation: | Department of Chemistry, Stanford University, Stanford, California 94305-5080, USA. |
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Abstract: | A strategy for the preparation of aconitine is described that attempts to exploit chemoselective C-H amination and the electrophilic reactivity of oxathiazinane N,O-acetals for assembling the complex, polycyclic carbon framework of the natural product. |
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