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| Hydrothermal Synthesis and Characterization of [V_(16)O_(38)(Cl)][Cu(enMe)_2]_(3.5)·2H_2O Containing {V_(16)O_(38)} Cluster | |
| 作者姓名： | CUI Xiao-bing ZHENG Shou-tian SUN Yan-qiong and YANG Guo-yu ** . Coordination and Hydrothermal Chemistry Group State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou P. R. China . State Key Laboratory of Coordination Chemistry Nanjing University Nanjing P. R. China |
| 作者单位： | CUI Xiao-bing 1，ZHENG Shou-tian 1，SUN Yan-qiong 1 and YANG Guo-yu 1，2** 1. Coordination and Hydrothermal Chemistry Group，State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，Chinese Academy of Sciences，Fuzhou 350002，P. R. China;2. State Key Laboratory of Coordination Chemistry，Nanjing University，Nanjing 210093，P. R. China |
| 基金项目： | SupportedbytheNationalNaturalScienceFoundationofChina(No .2 0 2 710 5 0and 2 0 1710 4 5 ) ,theTalentsProgramofChineseAcademyofSciencesandtheNaturalScienceFoundationofFujianProvince(No .E0 2 10 0 2 9) |
| 摘 要： | IntroductionBasedonarelativelylargenumberofdifferenttypesofbuildingblockswhichcorrespondtopolyhe dron {VOx} (x =4 ,5 ,6 ) ,polyoxovanadatesshowanextraordinaryvarietyofstructures ,suchascage ,basket ,belt ,ballandbarrelstructures1— 5] .Further more,these polyoxovanadatesexhibita pronouncedtendencytoformcage likestructureswhichmayen capsulateneutralmoleculesaswellasionicguests ,afeaturesharedbysomeisopolyanionssuchas V18O4 2·(H2 O) ]12 - 6 ] ,H4 V18O4 2 (X) ]9- (X =Cl- ,Br- ,I- ) 2 ,… |
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