| Towards Single-component Molecular Conductor [Ni（dmit）2 ] by Charge Disproportionation： 2[Ni（dmit）2]^0.5→[Ni（dmit）2 ]＋ [Ni（dmit）2]^- |
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| 引用本文： | QiFANG HongLEI WenXU. Towards Single-component Molecular Conductor [Ni（dmit）2 ] by Charge Disproportionation： 2[Ni（dmit）2]^0.5→[Ni（dmit）2 ]＋ [Ni（dmit）2]^-[J]. 中国化学快报, 2003, 14(11): 1109-1112 |
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| 作者姓名： | QiFANG HongLEI WenXU |
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| 作者单位： | [1]StateKeyLaboratoryofCrystalMaterials,ShandongUniversity,Jinan250100 [2]SchoolofInformationScienceandEngineering,ShandongUniversity,Jinan250100 |
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| 基金项目： | 国家自然科学基金，State Key Program of China |
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| 摘 要： | A new method of synthesizing single-component molecular conductor [Ni(dmit)2] bythe reaction 2(Me4N)[Ni(dmit)2]2→ [Ni(dmit)2] (Me4N)[Ni(dmit)2] is reported. [Ni(dmit)2]exhibits a semiconductive behavior above 167 K, while from 167 K down to the measuring limit of 60 K, it exhibits metallic conductivity.
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| 关 键 词： | 单组分分子半导体 2[Ni（dmit）2]^0.5 Ni（dmit）2 合成 [Ni（dmit）2]^- 镍配合物 不对称电荷 分子结构 |
Towards Single-component Molecular Conductor [Ni(dmit)2] by Charge Disproportionation:2[Ni(dmit)2]-0.5 →[Ni(dmit)2 ]+ [Ni(dmit)2]- |
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| Qi FANG,Hong Lei,Wen XU. Towards Single-component Molecular Conductor [Ni(dmit)2] by Charge Disproportionation:2[Ni(dmit)2]-0.5 →[Ni(dmit)2 ]+ [Ni(dmit)2]-[J]. Chinese Chemical Letters, 2003, 14(11): 1109-1112 |
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| Authors: | Qi FANG Hong Lei Wen XU |
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| Abstract: | A new method of synthesizing single-component molecular conductor [Ni(dmit)2] by the reaction 2(Me4N)[Ni(dmit)2]2→[Ni(dmit)2] + (Me4N)[Ni(dmit)2] is reported. [Ni(dmit)2] exhibits a semiconductive behavior above 167 K, while from 167 K down to the measuring limit of 60 K, it exhibits metallic conductivity. |
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| Keywords: | Single-component molecular conductors conductivity charge disproportionation |
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