| 顶空气相色谱在化学研究中的应用 |
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| 引用本文： | 吴瑛,付时雨,柴欣生. 顶空气相色谱在化学研究中的应用[J]. 广州化学, 2008, 33(2): 59-66 |
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| 作者姓名： | 吴瑛 付时雨 柴欣生 |
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| 作者单位： | 岳阳职业技术学院,湖南,岳阳,414000;华南理工大学,制浆造纸工程国家重点实验室,广东,广州,510640;华南理工大学,制浆造纸工程国家重点实验室,广东,广州,510640;佐治亚理工学院,造纸科学技术研究院,Atlanta,GA 30332,USA |
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| 摘 要： | 顶空气相色谱（headspace gas chromatography，简称HSGC）是将顶空样品预处理系统（headspace）和气相色谱结合使用的技术，具有简单、迅速、准确和自动化等优点，已经在商品检测、药品检测等常规检测中发挥重要作用。巧妙利用其顶空系统可以在化学分析测定中发挥更大的作用，能够测定挥发性化学物质的气液平衡常数（亨利常数）、无机盐的溶解度、高分子聚合过程单体含量等，还可解决化工工程样品分析中的复杂问题，以及应用于环境和其它工业过程化学成分含量的分析。
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| 关 键 词： | 顶空 气相色谱 气液平衡常数 |
Application of Headspace Gas Chromatography Technology in Chemistry Research |
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| WU Ying,FU Shi-yu,CHAI Xin-sheng. Application of Headspace Gas Chromatography Technology in Chemistry Research[J]. Guangzhou Chemistry, 2008, 33(2): 59-66 |
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| Authors: | WU Ying FU Shi-yu CHAI Xin-sheng |
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| Affiliation: | WU Ying, FU Shi-yu, CHAI Xin-sheng ( 1. YueyangTcchnical College, Yueyang 300222, Hunan, China; 2. State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, GuangzhouS10640, Guangdong, China; 3. Institute of Paper Sci. ＆ Tech., Georgia Institute of Technology, Atlanta, GA 30332, USA) |
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| Abstract: | Several headspace gas chromatographic(HSGC) techniques that can determine not only volatile species content but also their vapor-liquor equilibrium partitioning coefficients in the pulp and paper industrial samples with very complicated matrices were reviewed.The capability of HSGC for indirectly determination of non-volatile species through a phase conversion reaction method was also reported.Although the examples presented in this paper were more focused in the pulp and paper related application,HSGC technique has a great potential to be used for solving many very challenged problems in the other industries and research fields due to its accurate,rapid,simple,and automatic characteristics. |
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| Keywords: | headspace gas chromatography Henry constant |
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