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| 氮杂酞菁铜aza-CuPc的合成与晶体结构 | |
| 引用本文： | 姜文海,王旭,马春雨,于书坤,叶开其,常玉春,杜国同. 氮杂酞菁铜aza-CuPc的合成与晶体结构[J]. 高等学校化学学报, 2006, 27(12): 2263-2265 |
| 作者姓名： | 姜文海 王旭 马春雨 于书坤 叶开其 常玉春 杜国同 |
| 作者单位： | 1. 吉林大学集成光电子国家重点实验室,长春,130012 2. 吉林大学超分子结构与材料教育部重点实验室,长春,130012 3. 大连理工大学三束材料改性国家重点实验室,大连,116023 4. 吉林大学集成光电子国家重点实验室,长春,130012;大连理工大学三束材料改性国家重点实验室,大连,116023 |
| 摘 要： | 本文报道在固相条件下合成氮杂酞菁铜原料, 借助同步辐射光源进行单晶结构测试, 通过物理方法获得了其单晶结构数据. |
| 关 键 词： | 固相法合成 氮杂酞菁铜 同步辐射 晶体结构 |
| 文章编号： | 0251-0790（2006）12-2263-03 |
| 收稿时间： | 2006-02-22 |
| 修稿时间： | 2006-02-22 |
Synthesis and Crystal Structure of Azaanalog of Copper Phthalocyanine |
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| JIANG Wen-Hai,WANG Xu,MA Chun-Yu,YU Shu-Kun,YE Kai-Qi,CHANG Yu-Chun,DU Guo-Tong. Synthesis and Crystal Structure of Azaanalog of Copper Phthalocyanine[J]. Chemical Research In Chinese Universities, 2006, 27(12): 2263-2265 | |
| Authors: | JIANG Wen-Hai WANG Xu MA Chun-Yu YU Shu-Kun YE Kai-Qi CHANG Yu-Chun DU Guo-Tong |
| Affiliation: | 1. State Key Laboratory on Integrated Optoelectronics, Jilin University, Changchun 130012, China; 2. Key Laboratory for Superamolecular Structure and Materials of Ministry of Education, Jilin University, Changchun 130012, China; 3. State Key Laboratory of Materials Modification by Laser, Ion and Electron Beams, Dalian University of Technology, Dalian 116023, China |
| Abstract: | The azaanalog of copper phthalocyanine(aza-CuPc) complex C24H8CuN16 was prepared by the so-lid phase synthesis technology and its single crystals was characterized by high power X-ray from the synchrotron radiation. The crystal belongs to monoclinic system, space group P21/n with a=1.612 3(3) nm, b=0.529 40(11) nm, c=1.906 4(4) nm, β=105.25(3)°, V=1.569 9(5) nm, Z=2, Mr=584.00, Dc=1.235 g/cm3, F(000)=586, the final R=0.063 1 and wR=0.153 9 for 757 observed reflections with I>2σ(I), GOF=1.340. |
| Keywords: | Solid phase synthesis Azaanalog of copper phthalocyanine Synchrotron radiation Crystal structure |
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