| Synthesis and Crystal Structure of Bis(S-methyl-β-N- (4-dimethylaminophenyl)methlenedithiocarbazate) Nickel (Ⅱ) |
| |
| 引用本文： | BIAN Zheng-Wei(Chemistry Department,Jiangsu Educational Institute. Nanjing,210013)DUAN Chun-Ying ,THOMAS C. W. Mak(Coordination Chemistry Institute and State Key Laboratory ofCoordination Chemistry,Nanjing University,Nanjing 210093). Synthesis and Crystal Structure of Bis(S-methyl-β-N- (4-dimethylaminophenyl)methlenedithiocarbazate) Nickel (Ⅱ)[J]. 结构化学, 1997, 0(4) |
| |
| 作者姓名： | BIAN Zheng-Wei(Chemistry Department Jiangsu Educational Institute. Nanjing 210013)DUAN Chun-Ying THOMAS C. W. Mak(Coordination Chemistry Institute and State Key Laboratory ofCoordination Chemistry Nanjing University Nanjing 210093) |
| |
| 作者单位： | BIAN Zheng-Wei(Chemistry Department，Jiangsu Educational Institute. Nanjing，210013)DUAN Chun-Ying ;THOMAS C. W. Mak(Coordination Chemistry Institute and State Key Laboratory ofCoordination Chemistry，Nanjing University，Nanjing 210093) |
| |
| 摘 要： | 11NTRoDUCT1ONRecently,transitionmetalorganometallicandcoordinationcomplexeshavee-mergedaspotentialbuildingblocksfornonlinearoptical(NLO)materials(l-5i.Com-paredwlthorganlcmolecu1es,metalcomplexesofferalargervarietyofstructures,comparabIeor,insomecases,higherenvironmenta1stabilityandamuchgreaterdi-versityoftunableelectronicpropertiesbythevirtueofthecoordinatedmetalcen-tert6i.Thethio-Schiffbaseligandderivedfromdithiocarbazatesandthiosemicar-bazidescancoordinatereadilywithtransitionmetalstog…
|
| 关 键 词： | sulphur-nitrogen donor Schiff-base nickel (Ⅱ) complex crystal structure |
Synthesis and Crystal Structure of Bis(S-methyl-β-N- (4-dimethylaminophenyl)methlenedithiocarbazate) Nickel (Ⅱ) |
| |
| BIAN Zheng-Wei. Synthesis and Crystal Structure of Bis(S-methyl-β-N- (4-dimethylaminophenyl)methlenedithiocarbazate) Nickel (Ⅱ)[J]. Chinese Journal of Structural Chemistry, 1997, 0(4) |
| |
| Authors: | BIAN Zheng-Wei |
| |
| Abstract: | Reaction of nickel (Ⅱ) acetate with S-methyl-β-N-(4 dimethy-laminophenyl) methlenedithiocarbazate gave a mononuclear complex [Ni (C11H14N3S2)2]. Crystal of the title compound belongs to monoclinic systern,space group C2/cwith cell parameters a= 18. 785 (1), b= 17. 274 (1 ), c= 8. 344 (1 ) A, β= 108. 64(2)°, V= 2565(1 ) A3, Z=4, Mr= 563. 36, Dc= 1. 459 g/cm3; μ=10. 05 cm-1 andF(000) = 1176. The final refinement with 2179 observed reflections is converged withR= 0. 044 and R.= 0. 069. X-ray crystal structure analysis revealed that the coordina-tion geometry of Ni (Ⅱ) is a square-planar with two equivalent Ni -N and Ni - Sbonds. The Schiff-base ligand loses a proton from its tautomeric thiol form and is coor-dinated to the nickel atom via the mercapto sulphur and the β-nitiogen. |
| |
| Keywords: | sulphur-nitrogen donor Schiff-base nickel (Ⅱ) complex crystal structure |
| 本文献已被 CNKI 等数据库收录！ |
