Catalytic hydrocondensation of carbon monoxide with olefins and their hydropolymerization under the influence of carbon monoxide and hydrogen |
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Authors: | Ya. T. Éidus A. L. Lapidus V. I. Mashinskii L. L. Krasnova |
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Affiliation: | 1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow
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Abstract: | 1. | The activity of cobalt-group II metal oxide catalysts in the hydropolymerization reactions of C2-C4 olefins, initiated by CO at 190°, depends on the nature of the oxide and decreases when going from BeO to BaO. | 2. | In their reactivity the olefins fall into the order: C2 > C3H6 >-C4H8 > i-C4H8. | 3. | The degree of reduction of the cobalt found in the catalyst depends on the nature of the employed oxide and (toes not determine its activity. |
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