| 具有Cl…Cl作用的一维链状有机锡配合物——二(对氯苄基)氯化锡吡咯烷氨荒酸酯的合成、表征及晶体结构 |
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| 引用本文： | 尹汉东,洪 敏.具有Cl…Cl作用的一维链状有机锡配合物——二(对氯苄基)氯化锡吡咯烷氨荒酸酯的合成、表征及晶体结构[J].无机化学学报,2004,20(3):297-300. |
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| 作者姓名： | 尹汉东 洪 敏 |
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| 作者单位： | 聊城大学化学系,聊城,252059 |
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| 基金项目： | 国家自然科学基金资助项目(No.20271025)，山东省自然科学基金资助项目(No.L2003B01)。 |
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| 摘 要： | A novel complex, chlorodi(p-chlorbenzyl)tin dithiotetrahydropyrrolocarbamate, has been synthesized. The crystal structure has been determined by X-ray single crystal diffraction. The crystal of the complex belongs to monoclinic with space group C2/c, a=3.070 0(19) nm, b=0.787 9(5) nm, c=2.374 9(15) nm, β=119.63(9) °, Z=8, V=4.993(5) nm3, Dc=1.515 g·cm-3, μ=1.521 mm-1, R1=0.047 4, wR2=0.097 2. The structure of the complex consists of discrete molecule containing five-coordinate tin atom in a seriously distorted trigonal bipyramidal configuration. The molecules are packed in the unit cell in one-dimensional chain polymer through a weak interaction between the chlorine atoms of the adjacent molecules. CCDC: 220743.
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| 关 键 词： | 二(对氯苄基)二氯化锡 吡咯烷氨荒酸酯 Cl…Cl作用 晶体结构 |
| 修稿时间： | 2003年7月2日 |
Synthesis, Characterization and Crystal Structure of the Cl…Cl Interaction One-dimensional Chain Organotin Complex-- Chlorodi(p-chlorbenzyl)tin Dithiotetrahydropyrrolocarbamate |
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| YIN Han-Dong and HONG Min.Synthesis, Characterization and Crystal Structure of the Cl…Cl Interaction One-dimensional Chain Organotin Complex-- Chlorodi(p-chlorbenzyl)tin Dithiotetrahydropyrrolocarbamate[J].Chinese Journal of Inorganic Chemistry,2004,20(3):297-300. |
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| Authors: | YIN Han-Dong and HONG Min |
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| Institution: | Department of Chemistry, Liaocheng University, Liaocheng 252059 and Department of Chemistry, Liaocheng University, Liaocheng 252059 |
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| Abstract: | |
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| Keywords: | di(p-chlorbenzyl)tin dichloride dithiotetrahydropyrrolocarbamate Cl Cl interaction crystal structure |
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