Cross-coupling of benzylic acetates with arylboronic acids: one-pot transformation of benzylic alcohols to diarylmethanes |
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| Authors: | Kuwano Ryoichi Yokogi Masashi |
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| Affiliation: | Department of Chemistry, Graduate School of Sciences, Kyushu University, Higashi-ku, Fukuoka, Japan. rkuwascc@mbox.nc.kyushu-u.ac.jp |
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| Abstract: | Benzylic acetates reacted with arylboronic acids in the presence of a DPEphos-[Pd(eta3-C3H5)Cl]2 catalyst when tert-amyl alcohol was used as a solvent, and the catalytic cross-couplings produced diarylmethanes in high yields (up to 94% isolated yield). |
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