| 2,5-吡啶二羧酸及碳酸根构筑的三维Sm-Cu配合物的合成及晶体结构研究 |
| |
| 引用本文： | 王 卓,白凤英,邢永恒,施 展,谢 妍,赵海燕,候克玲.2,5-吡啶二羧酸及碳酸根构筑的三维Sm-Cu配合物的合成及晶体结构研究[J].无机化学学报,2010,26(4):713-716. |
| |
| 作者姓名： | 王 卓 白凤英 邢永恒 施 展 谢 妍 赵海燕 候克玲 |
| |
| 作者单位： | 1. 辽宁师范大学化学化工学院,大连,116029
2. 吉林大学化学学院,无机合成与制备化学国家重点实验室,长春,130012 |
| |
| 基金项目： | 国家自然科学基金，辽宁省教育厅2007度创新团队计划，无机合成与制备化学国家重点实验室 |
| |
| 摘 要： | <正>近年来,以多羧酸为配体的稀土-过渡金属配位聚合物由于其拓扑结构的多样性和在磁性、催化、化学吸附、光学性质和电子导体等方面的功能特性已经受到研究人员的广泛关注1-5]。由于稀土元素与过渡元素相比较他们具有各自不同的配位模
|
| 关 键 词： | Sm-Cu 配合物 2，5-吡啶二羧酸 水热合成 晶体结构 |
Synthesis, Structure of a 3D Sm-Cu Complex Based on 2,5-Pyridinedicarboxylate Acid and Carbonate Ligands |
| |
| WANG Zhuo,BAI Feng-Ying,XING Yong-Heng,SHI Zhan,XIE Yan,ZHAO Hai-Yan and HOU Ke-Ling.Synthesis, Structure of a 3D Sm-Cu Complex Based on 2,5-Pyridinedicarboxylate Acid and Carbonate Ligands[J].Chinese Journal of Inorganic Chemistry,2010,26(4):713-716. |
| |
| Authors: | WANG Zhuo BAI Feng-Ying XING Yong-Heng SHI Zhan XIE Yan ZHAO Hai-Yan and HOU Ke-Ling |
| |
| Institution: | College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029,College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029,College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029,State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012,College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029,College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029 and College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029 |
| |
| Abstract: | A complex {Sm_2Cu(pydc)_2(CO_3)_2(H_2O)_2]·2H_2O}_n(H_2pydc=2,5-pyridinedicarboxylate acid)was synthesized by hydrothermal condition.It was characteristic by elemental analysis,IR spectroscopy,and single-crystal X-ray diffraction.The structure of the complex reveals that it is a three-dimensional framework.The crystal belongs to monoclinic system,space group P2_1.The cell parameters are:α=0.960 8(2)nm,b=0.789 6(2)nm,c=1.551(3)nm,β=101.85(3)°,V=1.151 9(4)nm~3,Z=2.The Sm ions and CO_3~(2-) formed an infinite 2D plane,the plane connected by 2,5-pyridine dicarboxylic acid and copper ions,formed a 3D structure with micro-channel.CCDC:736228. |
| |
| Keywords: | Sm-Cu complexes 2 5-pyridinedicarboxylate Hydrothermal condition crystal structure |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
| 点击此处可从《无机化学学报》下载免费的PDF全文 |
|
