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纳米氧化钕的制备及其催化性能的研究
引用本文:徐宏,蔡弘华,罗仲宽,任祥忠,刘剑洪,陈沛,赵凤起,田德余.纳米氧化钕的制备及其催化性能的研究[J].无机化学学报,2003,19(6):627-630.
作者姓名:徐宏  蔡弘华  罗仲宽  任祥忠  刘剑洪  陈沛  赵凤起  田德余
作者单位:1. 深圳大学师范学院化生教育系,深圳,518060
2. 西安近代化学研究所,西安,710065
3. 深圳大学师范学院化生教育系,深圳,518060;国防科技大学航天与材料工程学院,长沙,410073
基金项目:高等学校骨干教师资助计划项目(No.教育育部科技司犤2000犦65号)。
摘    要:Nanometer-sized neodymium oxide has been synthesized by humid solid state reaction at room temperature, and characterized by scanning electron microscope, laser light scattering and X-ray diffraction. The effects of nanometer -sized neodymium oxide on catalyzing thermal decomposition reaction of hexogen (cyclotrimethylenetriamine, RDX) and absorbent powder (nitrocellulose absorbed nitroglycerin, NC/NG) have been investigated by DSC method. The mechanism of these catalytic reactions has also been proposed. The experimental results show that nanometer-sized neodymium oxide can catalyze the decomposition reaction of RDX and NC/NG effectively. The experimental results further suggest that nanometer-sized neodymium oxide is a potentially useful combustion catalyst of nitroamine propellant.

关 键 词:纳米材料  氧化钕  催化剂  黑索今  吸收药  热分解
修稿时间:2002年12月5日

Synthesis and Combustion Catalysis of Nanometer-sized Neodymium Oxide
XU Hong,CAI Hong-Hu,LUO Zhong-Kuan,REN Xiang-Zhong,LIU Jian-Hong,CHEN Pei,ZHAO Feng-Qi and TIAN De-Yu.Synthesis and Combustion Catalysis of Nanometer-sized Neodymium Oxide[J].Chinese Journal of Inorganic Chemistry,2003,19(6):627-630.
Authors:XU Hong  CAI Hong-Hu  LUO Zhong-Kuan  REN Xiang-Zhong  LIU Jian-Hong  CHEN Pei  ZHAO Feng-Qi and TIAN De-Yu
Abstract:Nanometer sized neodymium oxide has been synthesized by humid solid state reaction at room temperature, and characterized by scanning electron microscope, laser light scattering and X ray diffraction. The effects of nanometer sized neodymium oxide on catalyzing thermal decomposition reaction of hexogen (cyclotrimethylenetriamine, RDX) and absorbent powder (nitrocellulose absorbed nitroglycerin, NC/NG) have been investigated by DSC method. The mechanism of these catalytic reactions has also been proposed. The experimental results show that nanometer sized neodymium oxide can catalyze the decomposition reaction of RDX and NC/NG effectively. The experimental results further suggest that nanometer sized neodymium oxide is a potentially useful combustion catalyst of nitroamine propellant.
Keywords:nanometer material  neodymium oxide  catalyst    hexogen  absorbent powder  thermal decomposition
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