Electronic Raman spectra of iron doped MgO |
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Authors: | A. Poirier D. Walsh L.A. Boatner |
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Affiliation: | Rutherford Physics Building, McGill University, 3600 University Street, Montreal, Quebec, Canada H3A 2T8;Solid State Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37830, U.S.A. |
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Abstract: | The nearby excited states of Fe2+ in MgO are investigated by Raman spectroscopy. We observed an A1g impurity mode (185 cm?1) and an electronic transition at 110.5 ± 0.8 cm?1 which we associate with the first excited states of the ferrous ion, Γ3 and Γ4, previously observed by far infrared optical absorption. |
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