Far-infrared photoconductivity spectra of quenched-in acceptors in germanium: Chemical effects on the SA1 acceptors

Far-I.R. photoconductivity reveals the existence of at least four different kinds of SA₁ acceptors in germanium quenched from T > 800 each acceptor producing two or more hydrogenic excitation line series. One acceptor is correlated with the presence of Ni, another one with strong Cu contamination. The two other acceptors, which we call ‘normal’ and ‘shifted’, occur in samples quenched without intentional doping. The experiments indicate that the SA₁ acceptors in germanium are impurity complexes involving fast diffusing elements. We discuss a model according to which the SA₁ acceptors would be interstitial-substitutional pairs of transition metals. In particular, we propose to assign the ‘normal’ SA₁ acceptors to Fe_I-Cu_S pairs.