Low-temperature oxidative chlorination of methane over supported platinum chloride catalyst |
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| Authors: | V. P. Tretyakov G. P. Zimtseva E. S. Rudakov A. N. Osetskii |
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| Affiliation: | (1) Institute of Physical Organic and Coal Chemistry, Donetsk, USSR |
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| Abstract: | The PtII (catalyst)+PtIV (oxidant) system with a deficiency of Cl ligands is active in the oxidative chlorination of alkanes not only in aqueous solutions but also in the SiO2-supported state. In heterogeneous as well as in homogeneous conditions, the reaction proceeds at 100°C through platinum-alkyl intermediates.
       : PtII-     PtIV-     Cl-   ,      , SiO2.  , ,  100°   - .
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