| Synthesis and Crystal Structure of a Dinuclear Cu(Ⅱ) Complex [Cu(C_(13)H_9N_2O)Cl]_2·(CH_3CN)_2 with Ligand 2-Benzimidazol |
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| 引用本文： | LI Qing-Xianga,b② YANG Xiang-Liangb XU Hui-Bib a.Synthesis and Crystal Structure of a Dinuclear Cu(Ⅱ) Complex [Cu(C_(13)H_9N_2O)Cl]_2·(CH_3CN)_2 with Ligand 2-Benzimidazol[J].结构化学,2007,26(2):149-152. |
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| 作者姓名： | LI Qing-Xianga b② YANG Xiang-Liangb XU Hui-Bib a |
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| 作者单位： | LI Qing-Xianga，b② YANG Xiang-Liangb XU Hui-Bib a (Hubei Key Laboratory of Novel Chemical Reactor and Green Chemical Technology，Wuhan Institute of Technology，Wuhan 430073，China) b (College of Life Science，Huazhong University of Science and Technology，Wuhan 430074，China) |
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| 基金项目： | This work was supported by the National Natural Science Foundation of China (No. 20571058)，the Natural Science Foundation of Hubei Province (No. 2005ABA022)，the Science and Technology Tackle Key Foundation of Hubei Province (No. 2005AA401C54) |
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| 摘 要： | A new dinuclear copper complex, Cu(C13H9N2O)Cl]2·(CH3CN)2 (C30H24Cl2Cu2N6O2), has been synthesized and characterized by X-ray structure determination. It crystallizes in the tricli- nic system, space group P1, with a = 7.6677(14), b = 9.2375(17), c = 11.227(2) , α = 81.338(3), β = 88.173(4), γ = 66.199(3)o, V = 718.9(2) 3, Z = 1, Mr = 698.53, F(000) = 354, Dc = 1.613 g/cm3, μ(MoKα) = 1.705 mm-1, the final R = 0.0645 and wR = 0.1364 for 2474 unique reflections with 1809 observed ones (I > 2σ(I)). In the title complex, each copper(II) atom is located at the center of a distorted tetrahedron consisting of four coordinate atoms (one nitrogen atom, two oxygen anions, and one chlorine atom). Two copper(II) atoms are bridged by two oxygen anions (O(1) and O(1a)) of two phenolates to form a Cu(II)–Cu(II) binuclear entity, and the distance between two copper(II) atoms is 3.0144(15) .
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| 关 键 词： | 2-benzimidazol phenolate Cu(Ⅱ) complex crystal structure |
Synthesis and Crystal Structure of a Dinuclear Cu(Ⅱ) Complex [Cu(C_(13)H_9N_2O)Cl]_2·(CH_3CN)_2 with Ligand 2-Benzimidazol |
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| LI Qing-Xiang,YANG Xiang-Liang,XU Hui-Bi,.Synthesis and Crystal Structure of a Dinuclear Cu(Ⅱ) Complex [Cu(C_(13)H_9N_2O)Cl]_2·(CH_3CN)_2 with Ligand 2-Benzimidazol[J].Chinese Journal of Structural Chemistry,2007,26(2):149-152. |
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| Authors: | LI Qing-Xiang YANG Xiang-Liang XU Hui-Bi |
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| Abstract: | A new dinuclear copper complex, Cu(C13H9N2O)Cl]2·(CH3CN)2 (C30H24Cl2Cu2N6O2), has been synthesized and characterized by X-ray structure determination. It crystallizes in the tricli- nic system, space group P1, with a = 7.6677(14), b = 9.2375(17), c = 11.227(2) , α = 81.338(3), β = 88.173(4), γ = 66.199(3)o, V = 718.9(2) 3, Z = 1, Mr = 698.53, F(000) = 354, Dc = 1.613 g/cm3, μ(MoKα) = 1.705 mm-1, the final R = 0.0645 and wR = 0.1364 for 2474 unique reflections with 1809 observed ones (I > 2σ(I)). In the title complex, each copper(II) atom is located at the center of a distorted tetrahedron consisting of four coordinate atoms (one nitrogen atom, two oxygen anions, and one chlorine atom). Two copper(II) atoms are bridged by two oxygen anions (O(1) and O(1a)) of two phenolates to form a Cu(II)–Cu(II) binuclear entity, and the distance between two copper(II) atoms is 3.0144(15) . |
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| Keywords: | 2-benzimidazol phenolate Cu(II) complex crystal structure |
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