Rheology of isothermally crystallized poly(butylene terephthalate) nanocomposites with clay loadings under the percolation threshold |
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| Authors: | Defeng Wu Chixing Zhou Ming Zhang |
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| Institution: | 1. School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu, 225002, China;2. School of Chemistry and Chemical Engineering, Shanghai Jiaotong University, Shanghai, 200240, ChinaSchool of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu, 225002, China;3. School of Chemistry and Chemical Engineering, Shanghai Jiaotong University, Shanghai, 200240, China |
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| Abstract: | This article describes the structural evolution of clay in poly(butylene terephthalate) nanocomposites (PCNs) with clay loadings lower than the percolation threshold during the isothermal crystallization process. The study of the structure and rheological properties has revealed that the intercalation and detachment levels of clay are enhanced in samples crystallized at a high temperature (210 °C), in contrast to those of the original PCN, and this results in the formation of a rheological percolation network. However, for PCNs crystallized at a low temperature (190 °C), the further structural evolution of the tactoids is very small. All the experimental results indicate that the morphologies of clay can further evolve during the crystallization process, but the evolution level is strongly dependent on the crystallization temperature. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 229–238, 2007 |
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| Keywords: | clay crystallization isothermal crystallization nanocomposites percolation network rheology poly(butylene terephthalate) (PBT) |
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