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Synthesis and characterization of a main‐chain‐type conjugated copolymer containing rare earth with photocrosslinkable group
Authors:Gui‐An Wen  Xing‐Rong Zhu  Lian‐Hui Wang  Jia‐Chun Feng  Rui Zhu  Wei Wei  Bo PEng  Qi‐Bing Pei  Wei Huang
Institution:1. Institute of Advanced Materials (IAM), Fudan University, Shanghai 200433, People's Republic of China;2. Institute of Polymer Science, Fujian Normal University, Fuzhou 350007, People's Republic of China;3. Department of Materials Science and Engineering, University of California, Los Angeles, California 90095‐1595;4. Institute of Advanced Materials (IAM), Nanjing University of Posts and Telecommunications, Nanjing 210003, People's Republic of ChinaInstitute of Advanced Materials (IAM), Fudan University, Shanghai 200433, People's Republic of China
Abstract:In this article, we report the design, synthesis, and characterization of a new main‐chain‐type rare earth‐containing conjugated polymer with photocrosslinkable group. The polymer is crosslinked photochemically by the addition of a photoinitiator to yield an absolute insoluble network. The optical properties of the resulting conjugated polymer were characterized in solution, film state, and after photocrosslinking. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 388–394, 2007.
Keywords:conjugated polymer  crosslinking  energy transfer  rare earth
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