| 昆虫性信息素的固相合成 |
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| 引用本文： | 陈家威.昆虫性信息素的固相合成[J].高分子通报,1990(1):19-26,33. |
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| 作者姓名： | 陈家威 |
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| 作者单位： | 湖北大学化学系 武汉 |
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| 摘 要： | 本综述阐明昆虫性信息素固相合成的最新成就。C.C.Leznoff 开创了昆虫性信息素的固相合成,并合成了一系列信息素。他以二醇为原料,以聚合物三苯甲基氯为保护剂。陈德恒等将保护剂改成聚合物三苯甲基氯硅烷,产率比前人有所提高。陈家威等大大改进了前两人的线路,简化了步骤,只抓住关键的一步进行固相合成,总产率比前人提高得更多。
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| 关 键 词： | 昆虫性信息素 固相合成 |
The synthesis of insect sex pheromones on solid phase |
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| Chen Jiawei.The synthesis of insect sex pheromones on solid phase[J].Polymer Bulletin,1990(1):19-26,33. |
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| Authors: | Chen Jiawei |
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| Abstract: | This review covers the development,recent research progressabout the synthesis of insect sex pheromones on solid phase.C.C.Leznoff,et.al.have synthesized a large scale of insect sex pheromones on solid phase.Heused polymeric trityl chloride as monofunctional protecting reagent of diol.ButChan Tak Hang,et.al.changed the polymeric protecting reagent into polymer-bound triphenyl chlorosilane.Its yield is higher than before.Chen Jia Wei,et.al.modified above two methods:simplified the steps,only seized the keystep on solid phase.The yield also increased much more than above route. |
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| Keywords: | polymer-support solid phase synthesis polymeric wittig reagent polymeric protecting reagent insect sex pheromone |
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