Study of homogenous hydrogenation of acetylene compounds withpara-hydrogen and Pd(0) and Pt(0) complexes byin situ NMR spectroscopy |
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| Authors: | E Sulman C Deibele and J Bargon |
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| Institution: | (1) Institute of Physical and Theoretical Chemistry, University of Bonn, Wegelerstrasse 12, D-53115 Bonn, Germany;(2) Department of Biotechnology and Chemistry, Tver Technical University, A. Nikitina 22, 170026 Tver, Russia |
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| Abstract: | η2 -C60Pd(PPh3)2, η2 -C60Pt(PPh3)2 and C2H4Pt(PPh3)2 have been used as catalysts for homogeneous hydrogenation of acetylene compounds enriched in para-hydrogen (p-H2). The study of the processes has been carried out byin situ NMR spectroscopy. It has been concluded that the nature of the substrate affects the intensity and patterns of polarization
signals. |
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| Keywords: | Buckminsterfullerene hydrogenation acetylene alcohols 1H-NMR spectroscopy |
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