Solvent-Induced Single-Crystal-to-Single-Crystal Transformation in Multifunctional Chiral Dysprosium(III) Compounds |
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Authors: | Jian Liu Xiao-Peng Zhang Tao Wu Bin-Bin Ma Tian-Wei Wang Cheng-Hui Li Yi-Zhi Li Xiao-Zeng You |
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Affiliation: | State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures , Nanjing 210093, People's Republic of China. |
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Abstract: | Two new enantiomeric ionic chiral dysprosium(III) compounds were designed and synthesized. These compounds show simultaneously the optical activity, ferroelectric effects, nonlinear-optical effects, and slow magnetic relaxation behavior. More interestingly, these compounds exhibit reversible single-crystal-to-single-crystal transformations associated with the release or absorption of solvent molecules. The structure transformations are accompanied by distinct changes in the physical properties. |
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