Porous CeO2 nanorod-catalyzed synthesis of poly-substituted imino-pyrrolidine-thiones |
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| Authors: | Yuanjiang Wang Wenhui Ge Yue Fang Xuanxuan Ren Shinian Cao Guixiang Liu Mingqi Li Jiangbiao Xu Yu Wan Xiguang Han Hui Wu |
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| Affiliation: | 1.School of Chemistry and Chemical Engineering,Jiangsu Normal University,Xuzhou,China;2.State Key Laboratory Cultivation Construction Base of Biotechnology on Med-edible Plant of Jiangsu Province,Jiangsu Normal University,Xuzhou,China;3.Kewen College,Jiangsu Normal University,Xuzhou,China |
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| Abstract: | Porous CeO2 nanorod has been used as efficient and recyclable heterogeneous catalyst for the synthesis of highly functionalized imino-pyrrolidine-thiones via the reaction of aromatic aldehyde (especially one bearing an electron-donating group), malononitrile, isocyanide and unactivated weakly acidic heterocyclic thiophenol. The high catalytic efficiency of porous CeO2 nanorod in this reaction was discussed preliminarily based on their morphology and structure. |
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