Chloro-Bridged Dimeric Cadmium(II)-Isothiocyanate Complex with a Tridentate NNN Type Ligand: Synthesis,X-ray Structure,Thermal Analysis |
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Authors: | Çiğdem Hopa Mahir Alkan Canan Kazak N Burcu Arslan Raif Kurtaran |
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Institution: | (1) Department of Chemistry, Faculty of Arts and Sciences, Balikesir University, Cagis, 10145 Balikesir, Turkey;(2) Department of Physics, Faculty of Arts and Sciences, Ondokuz Mayis University, 55139 Samsun, Turkey; |
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Abstract: | Abstract The dinuclear cadmium(II) complex with 2,6-bis(3,4,5-trimethyl-N-pyrazolyl)pyridine (btmpp) has been synthesized, and characterized by single crystal X-ray diffraction, IR, UV–Vis and TGA–DTA
methods. Cd atoms are located in a distorted octahedral environment in the complex. The complex crystalizes in monoclinic
space group C 2/c, with unit cell dimensions a = 20.5636(12) Å, b = 14.0167(13) Å, c = 15.6598(11) Å, β = 113.425(5)o, V = 4141.7(5) Å3. There are two intermolecular and a intramolecular hydrogen bonds interactions in crystal. |
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