Chirality manipulation of supramolecular self-assembly based on the host-guest chemistry of cyclodextrin |
| |
| Affiliation: | 1. Graduate School of Pharmaceutical Sciences, Kumamoto University, 5-1 Oe-honmachi, Chuo-ku, Kumamoto 862-0973, Japan;2. Program for Leading Graduate Schools “HIGO (Health Life Science: Interdisciplinary and Glocal Oriented) Program”, Kumamoto University, 5-1 Oe-honmachi, Chuo-ku, Kumamoto 862-0973, Japan;1. College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China;2. School of Earth & Space Science, Peking University, Beijing 100871, China;3. College of Science, China Agricultural University, Beijing 100193, China;1. Shaanxi Key Laboratory of Chemical Additives for Industry, College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi’an, 710021, China;2. MOE Key Laboratory of Material Physics and Chemistry Under Extraordinary Conditions and Shaanxi Key Laboratory of Macromolecular Science and Technology, School of Science, Northwestern Polytechnical University, Xi’an, 710072, China;3. Institute of Basic Medical Sciences, Xi''an Medical University, Xi''an, 710021, China;4. Xi’an Modern Chemistry Research Institute, Xi’an 710065, China;1. College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China;2. School of Earth & Space Science, Peking University, Beijing 100871, China;3. State Key Laboratory of Enhanced Oil Recovery, Research Institute of Petroleum Exploration and Development, Beijing 100083, China |
| |
| Abstract: | Chiral materials have been of the interests of scientists for nearly a century. People have endeavored a great effort to manipulate the chirality of various self-assembled materials. Among these efforts, cyclodextrins are used only in recent years, although it has long been recognized that the chirality of cyclodextrin can be transferred to the guest. In this review, we for the first time summarize the recent advancement of the supramolecular chirality manipulation on the basis of the host-guest chemistry of cyclodextrins. By using the simple Harata-Kodaka's rule, natural cyclodextrins can be exploited in a dynamic manner to create chirality inversion materials through crystalline self-assembly, which is facile and environment-friendly. What is more, we also discussed the remarks on future outlooks at the end of this article and expect it to stimulate a rapid development on both the theory and application level. |
| |
| Keywords: | Chirality manipulation Cyclodextrin Harata-Kodaka's rule Crystalline self-assembly |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
