| 两亲性芳香亚胺环钯化合物及其Langmuir-Blodgett膜的制备、表征及催化活性 |
| |
| 引用本文： | 赵娜,王飞,周梅玲,李铁生,刘辉,许文俭,吴养洁.两亲性芳香亚胺环钯化合物及其Langmuir-Blodgett膜的制备、表征及催化活性[J].催化学报,2013,34(8):1583-1588. |
| |
| 作者姓名： | 赵娜 王飞 周梅玲 李铁生 刘辉 许文俭 吴养洁 |
| |
| 作者单位： | 郑州大学化学与分子工程学院, 河南省化学生物与有机化学重点实验室, 郑州大学先进纳米信息材料实验室, 河南郑州450052 |
| |
| 基金项目： | supported by the National Natural Science Foundation of China (20973157);the Research and Development Foundation of Zhengzhou (094SGZG23056)~~ |
| |
| 摘 要： | 合成并表征了一系列新型两亲性芳香亚胺环钯化合物.结果显示,该系列环钯催化剂可高效催化均相条件下的Heck和Suzuki偶联反应.将两亲性芳香亚胺环钯二聚体制成LB膜,其在异相条件下的催化活性是均相条件下的25倍.
|
| 关 键 词： | 芳香亚胺 环钯催化剂 Langmuir-Blodgett膜 Suzuki反应 Heck反应 |
| 收稿时间： | 2013-04-20 |
Preparation,characterization and catalytic activity of amphiphilic cyclopalladated aryl imines and their Langmuir-Blodgett films |
| |
| Na Zhao,Fei Wang,Meiling Zhou,Tiesheng Li #,Hui Liu,Wenjian Xu,Yangjie Wu.Preparation,characterization and catalytic activity of amphiphilic cyclopalladated aryl imines and their Langmuir-Blodgett films[J].Chinese Journal of Catalysis,2013,34(8):1583-1588. |
| |
| Authors: | Na Zhao Fei Wang Meiling Zhou Tiesheng Li # Hui Liu Wenjian Xu Yangjie Wu |
| |
| Institution: | Key Laboratory of Chemical Biology and Organic Chemistry of Henan Province, Key Laboratory of Advanced Nano-information Materials, College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450052, Henan, China |
| |
| Abstract: | A series of novel amphiphilic cyclopalladated aryl imines were synthesized and characterized. These catalysts showed high activity for Heck and Suzuki reactions in homogeneous systems. Heterogeneous Langmuir-Blodgett films of the catalysts also demonstrated high catalytic activity for these coupling reactions. |
| |
| Keywords: | Aryl imine Cyclopalladated catalyst Langmuir-Blodgett film Suzuki reaction Heck reaction |
| 本文献已被 CNKI 等数据库收录！ |
| 点击此处可从《催化学报》浏览原始摘要信息 |
| 点击此处可从《催化学报》下载免费的PDF全文 |
