Aldol-type reactions between trimethylsilyl enol ethers and acetals with the aid of rhodium complex |
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| Authors: | Susumu Sato Isamu Matsuda Yusuke Izumi |
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| Affiliation: | Department of Synthetic Chemistry, Faculty of Engineering, Nagoya University, Chikusa, Nagoya 464, Japan |
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| Abstract: | Aldol-type reactions of trimethylsilyl enol ethers with acetals, ketals, and orthoesters are successfully performed with the aid of a catalytic amount of rhodium complex, Rh4(CO)12 or [Rh(COD)(DPPB)]+ClO4−, underneutral conditions. |
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