Abstract: | Molybdenum polyoxometallates with the buckyball structure, ((NH4)42Mo72VIMo60VO372(H3CCOO)30(H2O)72] · 30H3CCOONH4 · 250H2O (I), (NH4)42Mo72VIMo60VO372(ClCH2COO)30(H2O)72)] · 250H2O · 15ClCH2COONa (II), in particular, as parts of polymer-containing compositions were studied by EPR, NMR, IR, and Raman spectroscopy. The structural
and chemical aspects responsible for the formation of the observed spectra were considered. |