Two pathways for the protolysis of 1-(alkythio)-1-buten-3-ynes and the effect of cis-trans isomerism |
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| Authors: | A N Volkov A N Khuryakova R N Khudyakova V V Keiko B A Trofimov |
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| Institution: | (1) Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR |
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| Abstract: | Conclusions We have used a spectrophotometric method to examine the kinetics of the hydrolysis of 1-(alkylthio)-1-buten-3-ynes to (alkylthio)butenones and acetoacetaldehyde; the rate of reaction depends markedly on the reactant configuration.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 153–159, January, 1978. |
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