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Manipulating the cavity of a porous material changes the photoreactivity of included guests
Authors:Dewal Mahender B  Xu Yuewen  Yang Jun  Mohammed Fiaz  Smith Mark D  Shimizu Linda S
Affiliation:Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, USA.
Abstract:Changing an ether to a ketone within the framework of a bis-urea macrocycle has little effect on the supramolecular assembly of this building block into porous crystals but introduces a triplet sensitizer into the framework that dramatically alters the photochemical reactions of included guests.
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