| 烷氧取代聚对苯乙炔共聚物的合成 |
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| 引用本文： | 王建营,胡文祥,李银奎,龙永福.烷氧取代聚对苯乙炔共聚物的合成[J].高分子学报,1999,9(3):355-358. |
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| 作者姓名： | 王建营 胡文祥 李银奎 龙永福 |
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| 作者单位： | 1. 总装备部后勤部军事医学研究所9702信箱,北京,100101
2. 国防科技大学材料工程与应用化学系,长沙,410073 |
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| 摘 要： | 聚对苯乙炔（ＰＰＶ）及其衍生物具有独特的光电性能，也是到目前为止性能最好的电致发光材料［１］，用ＰＰＶ作发光层而装配的发光二极管（ＬＥＤ），具有制造方便、驱动电压低、亮度高等优点，可实现大面积、多色显示，成为电致发光领域研究的热点．ＰＰＶ及其衍生物的...
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| 关 键 词： | 聚对苯乙炔，烷氧取代基，共聚合 |
THE SYNTHESIS OF COPOLYMER OF POLY(p-PHENYLENE VINYLENE) SUBSTITUTED BY ALKOXYL GROUPS |
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| WANG Jianying,HU Wenxiang,LI Yinkui,LONG Yongfu.THE SYNTHESIS OF COPOLYMER OF POLY(p-PHENYLENE VINYLENE) SUBSTITUTED BY ALKOXYL GROUPS[J].Acta Polymerica Sinica,1999,9(3):355-358. |
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| Authors: | WANG Jianying HU Wenxiang LI Yinkui LONG Yongfu |
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| Abstract: | Poly(p\|phenylene vinylene)(PPV)and its derivatives have special optoelectronics properties and have aroused great interest in the world as excellent electroluminescent materials up to now.In this paper,a series of soluble PPV derivatives were synthesized by dehydrochlorination reaction with p\|methoxy phenol as raw materials.The results showed that attaching the longer alkoxy\|substitutes in benzene ring or applying copolymerization could improve the solubility of PPV derivatives and DMSO as a strong polar solvent could increase the yield of polymer.The structure of polymer was indentified by UV/Vis\,IR and \+\{1\}H\|NMR.\= |
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| Keywords: | Poly(p\|phenylene vinylene) Alkoxy\|substitutes Copolymerization |
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