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The Condensation of Aromatic Aldehydes with Acidic Methylene Compounds in Water
作者姓名:DaQingSHI  JingCHEN  QiYaZHUANG  XiangShanWANG  HongWenHU
作者单位:[1]DepartmentofChemistry,XuzhouNormalUniversity,Xuzhou221009 [2]DepartmentofChemistry,NanjingUniversity,Nanjing210093
摘    要:The condensation of aromatic aldehydes with acidic methylene compounds such as malononitrile, methyl cyanoacetate, cyanoacetamide, 5,5-dimethyl-1,3-cyclohexanedione,bartbituric acid and 2-thiobarbituric acid proceeded very efficiently in water in the presence of triethylbenzylammonium chloride (TEBA) and the products were isolated simply by filtration.

关 键 词:浓缩  芳香族醛  酸性亚甲基化合物    绿色化学  反应机理  催化剂

The Condensation of Aromatic Aldehydes with Acidic Methylene Compounds in Water
DaQingSHI JingCHEN QiYaZHUANG XiangShanWANG HongWenHU.The Condensation of Aromatic Aldehydes with Acidic Methylene Compounds in Water[J].Chinese Chemical Letters,2003,14(12):1242-1245.
Authors:Da Qing SHI  Jing CHEN  Qi Ya ZHUANG  Xiang Shan WANG  Hong Wen HU
Abstract:The condensation of aromatic aldehydes with acidic methylene compounds such as malononitrile, methyl cyanoacetate, cyanoacetamide, 5,5-dimethyl-1,3-cyclohexanedione, bartbituric acid and 2-thiobarbituric acid proceeded very efficiently in water in the presence of triethylbenzylammonium chloride (TEBA) and the products were isolated simply by filtration.
Keywords:Condensation  aromatic aldehyde  acidic methylene compound  water  green chemistry  
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