| 脯氨酸催化不对称羟醛缩合反应机理研究进展 |
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| 引用本文： | 樊建芬,孙云鹏,肖鹤鸣.脯氨酸催化不对称羟醛缩合反应机理研究进展[J].有机化学,2006,26(11):1463-1467. |
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| 作者姓名： | 樊建芬 孙云鹏 肖鹤鸣 |
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| 作者单位： | 1. 苏州大学化学化工学院江苏省有机合成重点实验室,苏州,215123
2. 南京理工大学化工学院,南京,210094 |
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| 基金项目： | 江苏省有机合成重点实验室开放课题(No．JSK010)资助项目． |
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| 摘 要： | 脯氨酸催化不对称直接羟醛缩合反应是近年来不对称合成研究的热点. 综述并讨论了分子内和分子间不对称直接羟醛缩合的反应机理及其微观过程.
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| 关 键 词： | 脯氨酸 不对称直接羟醛缩合 反应机理 |
| 收稿时间： | 07 18 2005 12:00AM |
| 修稿时间： | 03 3 2006 12:00AM |
Progress in the Study on the Reaction Mechanisms of Proline-Catalyzed Asymmetric Direct Aldol Reactions |
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| FAN,Jian-Fen,SUN,Yun-Peng,XIAO,He-Ming.Progress in the Study on the Reaction Mechanisms of Proline-Catalyzed Asymmetric Direct Aldol Reactions[J].Chinese Journal of Organic Chemistry,2006,26(11):1463-1467. |
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| Authors: | FAN Jian-Fen SUN Yun-Peng XIAO He-Ming |
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| Institution: | a Key Laboratory of Organic Synthesis of Jiangsu Province, Faculty of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215123;b Faculty of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094 |
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| Abstract: | Asymmetric direct aldol reaction is one of the central study issues in the field of asymmetric synthesis. In this review, reaction mechanisms of proline-catalyzed intra- and inter-molecular asymmetric aldol reactions are presented and discussed. |
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| Keywords: | proline asymmetric direct aldol reaction reaction mechanism |
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