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Empirical correlation equations describing retention data of hydrocarbons on dinonylphatalate and polyethyleneglycol 4000
Authors:K. Héberger
Affiliation:(1) Max-Planck-Institut für Strömungsforschung, Bunsenstr. 10, D-3400 Göttingen, FRG;(2) Present address: Central Research Institut for Chemistry of the Hungarian Academy of Sciences, P. O. Box 17, H-1525 Budapest, Hungary
Abstract:Summary Relative retention data and Kováts retention indices were measured for several hydrocarbons (mainly for alkylbenzenes) on dinonylphtalate and polyethylenelycol 4000 stationary phase. Correlations were searched between these retention data and the following physical (boiling point, molrefraction, molvolume) and topological (connectiviity index and general index of molecular complexity) properties of solutes. The best fitting equations was choosen among more than 150 equations involving linear, quadratic, exponential, two variables linear and quadratic dependence of retention data and the properties mentioned as well as their inverses.
Keywords:Gas chromatography  Structure-retention correlation  Ková  ts retention index  Alkylaromatics
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