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Magnetic entropy change and magnetic properties of LaFe_(11.5)Si_(1.5) after controlling the Curie temperature by partial substitution of Mn and hydrogenation
Institution:1. School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China; 2. College of Science, Tianjin University of Technology, Tianjin 300384, China
Abstract:Magnetic properties and magnetic entropy changes of La(Fe1-xMnx)11.5Si1.5Hy compounds are investigated. Their Curie temperatures are adjusted to room temperature by partial Mn substitution for Fe and hydrogen absorption in 1-atm (1 atm=1.01325×105 Pa) hydrogen gas. Under a field change from 0 T to 2 T, the maximum magnetic entropy change for La(Fe0.99Mn0.01)11.5Si1.5H1.61 is -11.5 J/kg. The suitable Curie temperature and large value of Δ Sm make it an attractive potential candidate for the room temperature magnetic refrigeration application.
Keywords:magnetic refrigeration  Curie temperature (TC)  hydrogen absorption  magnetocaloric effect (MCE)  
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