Metal-complex catalysis during the reduction of functional groups by sodium borohydride in the synthesis of pyrrolidine derivatives |
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| Authors: | A. O. Martirosyan V. E. Hovhanesyan S. P. Gasparyan S. S. Mamayan R. K. Ghazaryan V. N. Madakyan |
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| Affiliation: | (1) A. L. Mndzhoyan Institute of Fine Organic Chemistry, National Academy of Sciences of the Republic of Armenia, Erevan;(2) Center of Research on the Structure of Molecules, National Academy of Sciences of the Republic of Armenia, Erevan;(3) M. Heratsi Erevan Medical University, Erevan, Republic of Armenia |
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| Abstract: | A selective method was developed for the reduction of functional groups with sodium borohydride using complexes of CoCl2 and CuCl2 with triethylbenzylammonium chloride and cobalt and copper mesotetra[4-(2-hydroxyethyl)pyridyl]porphyrinates as catalysts. __________ Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 205–208, February, 2006. |
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| Keywords: | sodium borohydride copper and cobalt complexes metal-complex catalysis pyrrolidines porphyrins reduction |
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