Thiocarbonyl rhodium complexes with tricyclohexylphosphine and other nitrogen and phosphorus donor ligands |
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| Authors: | Rafael Usón Pascual Lahuerta Daniel Carmona Luis A. Oro |
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| Affiliation: | (1) Department of Inorganic Chemistry, University of Zaragoza, Zaragoza, Spain |
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| Abstract: | Summary The preparation of the covalent Rh(OCIO3)(CS)(PCy3)2 and Rh(OClO3)(CS)(PPh3)(PCy3) perchlorato complexes is described, These complexes react with mono- or bidentate nitrogen donor ligands to give new cationic complexes of the [Rh(CS)(PCY3)2L]ClO4 and [Rh(CS)(PPh,)(PCy3)L]ClO4 types, |
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