Terminal aziridines by alpha-deprotonation/electrophile trapping of N-protected aziridine |
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| Authors: | Hodgson David M Hughes Steven P Thompson Amber L Heightman Tom D |
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| Institution: | Department of Chemistry, Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford OX1 3TA, UK. david.hodgson@chem.ox.ac.uk |
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| Abstract: | N-tert-Butylsulfonyl and N-tert-butylsulfinyl aziridine undergo alpha-lithiation/electrophile trapping providing a new entry to terminal aziridines. With N-tert-butylsulfinyl aziridine complete asymmetric induction is observed alpha to nitrogen. |
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