Reversible emergence of a self-assembled layered structure from three-dimensional isotropic ionic crystal of a cluster compound (4-HNC5H4OH)2Mo6Cl14 driven by absorption of water and alcohols |
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| Authors: | Inumaru Kei Kikudome Takashi Fukuoka Hiroshi Yamanaka Shoji |
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| Affiliation: | Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, 1-4-1, Kagamiyama, Higashi-Hiroshima 739-8527, Japan. inumaru@hiroshima-u.ac.jp |
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| Abstract: | The compound comprising nanometer scale cluster molecules showed unusual reversible structural transformation between an isotropic ionic crystal and a layered structure of which the interlayer spaces are filled with the absorbed molecules. |
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