First optically active P-alkoxy derivative of palladated phosphacymantrene: synthesis,structure, and chiroptical properties |
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| Authors: | A. F. Smol’yakov A. G. Ginzburg V. V. Bashilov F. M. Dolgushin P. V. Petrovskii K. K. Babievsky V. I. Sokolov |
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| Affiliation: | 1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation
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| Abstract: | The solvopalladation reaction of 2,5-diphenylphosphacymantrene with Na2PdCl4, AcONa, and optically active carbinol (S)-(?)-2-methylbutanol was carried out. Optically active complex 3 was obtained and characterized by X-ray diffraction analysis and circular dichroism (CD), 13C and 31P NMR, IR, and UV spectra. |
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