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Platinum-catalyzed addition of iodomethane to acetylene |
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| Authors: | S A Mitchenko O V Khazipov T V Krasnyakova |
| Institution: | 1. L. M. Litvinenko Institute of Physicoorganic Chemistry and Coal Chemistry, National Academy of Sciences of Ukraine, 20 ul. R. Lyuksemburg, 83114, Donetsk, Ukraine 2. Luhansk Taras Shevchenko National University, 2 ul. Oboronna, 91011, Luhansk, Ukraine |
| Abstract: | The reaction of iodomethane and acetylene in the presence of PtII and NaI in acetone gives (E)-1-iodopropene. A possible mechanism involves the intermediate formation of a PtIV methyl vinyl derivative by the iodoplatination of acetylene with a reversibly formed a PtIV methyl complex and assumes the catalytic character of the process. |
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