Mononuclear copper(II)-hydroperoxo complex derived from reaction of copper(I) complex with dioxygen as a model of DbetaM and PHM |
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| Authors: | Fujii Tatsuya Yamaguchi Syuhei Funahashi Yasuhiro Ozawa Tomohiro Tosha Takehiko Kitagawa Teizo Masuda Hideki |
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| Affiliation: | Department of Applied Chemistry, Nagoya Institute of Technology, Showa-ku, Nagoya, 466-8555, Japan. |
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| Abstract: | A mononuclear copper(II)-hydroperoxo species has been generated by the reaction of Cu(I)-H2BPPA complex with dioxygen, which illustrates the enzymatic reaction process of the CuB site in the DbetaM and PHM. |
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