Synthesis and Single-crystal Structures of Two Copper(II) Complexes and One Iron(II) Complex Prepared by in situ Ligand Substitution at Room Temperature |
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| Authors: | Wei Huang Huifen Qian |
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| Institution: | (1) State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing, 210093, P.R. China;(2) College of Sciences, Nanjing University of Technology, Nanjing, 210009, P.R. China |
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| Abstract: | Two hexa-coordinate copper(II) complexes formulated as Cu(phen)(4-dmampy)2(ClO4)2] and Cu(bpy)(3-ampy)2(ClO4)2] · 0.5CH3OH · 0.5H2O (phen = 1,10–phenanthroline bpy = 2,2′-bipyridine, 3-ampy = 3-aminopyridine, 4-dmampy = 4-dimethylaminopyridine), and one
low-spin ferrous complex formulated as Fe(dmbpy)3](ClO4)2 · H2O (dmbpy = 4,4′-dimethyl-2,2′-bipyridine), were synthesized by in situ ligand substitution at room temperature, and characterized by X-ray single-crystal diffraction. This is the first structural
report where either 4-dmampy and phen molecules, or 3-ampy and bpy molecules, are located simultaneously around one metal
center. |
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